Method for preparing high molecular weight random...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carbohydrate or derivative as a reactant

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C528S335000, C528S336000, C528S351000, C525S540000, C525S926000

Reexamination Certificate

active

06894135

ABSTRACT:
High molecular weight random polyhydroxypolyamides (PHPAs) are produced by creating prepolymers which are further polymerized. Random prepolymers are formed from a stoichiometrically molar balance (1:1) starting material. The starting material is a 1:1 stoichiometrically balanced esterified aldaric acid:alkylene or alkylene derived diammonium salt. Alternatively, the starting material is an esterified stoichiometrically balanced diacid:diamine salt and a N′-ammoniumalkyl (or alkyl derived)-D-aldaramic acid terminal carboxylate zwitterionic salt mixture. The starting materials are polymerized in a basic alcohol using a second amine. The polymerized material, or the random prepolymers, are isolated and then further polymerized in a solvent, typically a mixed solvent of an alcohol and non-alcohol, to obtain the high molecular weight PHPAs.

REFERENCES:
patent: 4833230 (1989-05-01), Kiely et al.
patent: 5312967 (1994-05-01), Kiely et al.
patent: 5329044 (1994-07-01), Kiely et al.
patent: 5434233 (1995-07-01), Kiely et al.
patent: 5473035 (1995-12-01), Kiely et al.
Ogata, et al.; Synthesis of Hydrophilic Polyamide by Active Polycondensation; J. Polym. Sci., Polym. Lett. Ed. (1974) vol. 12, p. 355; Tokyo, JP.
Ogata, et al.; Synthesis of Hydrophilic Polyamide from L-Tartarate and diamines by Active Polycondensation; J. Polym. Sci., Polym. Chem. Ed. (1975) vol. 13, p. 1793; JP.
Ogata, et al.; Active Polycondensation of Diethyl 2,3,4,5- Tetrahydroxyadipate with Diamines; J. Polym. Sci., Polym. Chem. Ed., (1976), vol. 14, p. 783; Tokyo, JP.
Ogata, et al.; Copolycondensation of Hydroxyl Diesters and Active Diesters with Hexamethylenediamine; J. Polym. Sci., Polym. Chem. Ed (1977) vol. 15, p. 1523; Tokyo, JP.
Ogata, et al.; Synthesis of Polyamides through Active Diesters; J. Polym. Sci., Polym. Chem. Ed. (1973) vol. 11, p. 1095; Tokyo, JP.
Ogata, et al.; Synthesis of Polyesters from Active Diesters; J. Polym. Sci., Chem. Ed. (1973) vol. 11, p. 2537; Tokyo, JP.
Ogata; New Polycondensation Systems; Polym. Prepr. (1976) vol. 17, p. 151; Tokyo, JP.
Ogata, et al.; Polycondensation Rxn of Dimethyl Tartrate with Hexamethylenediamine in the Presence of Various Matrices; J. Polym. Sci., Polym. Chem. Ed. (1980) vol. 18, p. 939.
Lin; Diverse Applications of Carbohydrate Acids in Organic Synthesis, a Dissertation; Univ. of Alabama at Birmingham (1987).
Chen; Experimental and Theoretical Studies Concerned with Synthetic Acyclic Carbohydrate Based Polyamides, a Dissertation; Univ. of Alabama at Birmingham (1992).
Kiely, et al; Hydorxylated Nylons Based on Unportected Esterified D-Glucaric Acid by Simple Condensation Reactions; J. Am. Chem. Soc. (1994) vol. 116, p. 571; Birmingham, AL.
MURAKI: Polyamides; SciFinder Scholar; Patent No. JP 48032997 A2 (1973).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method for preparing high molecular weight random... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method for preparing high molecular weight random..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method for preparing high molecular weight random... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3446442

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.