Method for preparing graft copolymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525259, 525261, 525273, 525309, 525244, 525249, 526185, 526194, 526217, 526225, C08F26506, C08F22018

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053367251

ABSTRACT:
A method for preparing a graft copolymer is here disclosed which is characterized by comprising the step of carrying out a living polymerization of at least one (meth)acrylic ester by the use of a polymeric compound as an initiator having one or more units represented by the following formula (I) in a molecular chain substantially in the absence of water in the presence of a Lewis acid or a donor compound of an anion selected from the group consisting of HF.sub.2.sup.-, (CH.sub.3).sub.3 SiF.sub.2.sup.- and F.sup.- : ##STR1## wherein R is hydrogen or an alkyl group having 1 to 6 carbon atoms, and R' is an alkyl group having 1 to 12 carbon atoms.

REFERENCES:
patent: 4940760 (1990-07-01), Boettcher et al.
patent: 5126882 (1992-06-01), Makoto et al.
Odian, G. "Principles of Polymerization". N.Y. John Wiley & Sons, Inc., 1991, pp. 407-408.

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