Method for preparing dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,

Details Method for preparing dodecahydro-3a,6,6,9a-tetramethylnaphtho[2, Method for preparing dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,

1995-07-17

1996-11-05

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

549389, 549560, C07C 69013, C07D31192, C07D30314

Patent

active

055719392

ABSTRACT:
The method is directed to the preparation of dodecohydro-3a,6,6,9a-tetramethyl-naphtho[2,1-b]furan from sclareol using an alkoxy-radical fragmentation reaction. A novel 9-haloethyl decalin derivative is an intermediate in this method.

REFERENCES:
patent: 2181085 (1939-11-01), Alquist et al.
patent: 3029255 (1962-04-01), Stoll
patent: 3050532 (1962-08-01), Schumacher et al.
patent: 3671587 (1972-06-01), Troxler et al.
patent: 3989739 (1976-11-01), Stadler et al.
patent: 5235098 (1993-08-01), Christenson
patent: 5434300 (1995-07-01), Christenson
Cambie et al., Aust. J. Chem., 24, pp. 583-591 (1971).

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