Method for preparing di(organo) esters of pyrocarbonic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters

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558260, 558270, 558274, 558277, C07C 6996

Patent

active

052312119

ABSTRACT:
Di(organo) esters of pyrocarbonic acid, e.g., dialkyl pyrocarbonates, such as diethyl pyrocarbonate, are prepared by reaction of the corresponding organohaloformate with aqueous alkali metal hydroxide, e.g., sodium hydroxide, in the substantial absence of an organic solvent and in the presence of a catalytic amount of a bis[poly(oxy(C.sub.2 -C.sub.4)alkylene)] C.sub.6 -C.sub.20 aliphatic amine, e.g., coco bis(polyoxyethylene) amine.

REFERENCES:
patent: 3326958 (1992-12-01), Curtius
patent: 4929748 (1992-12-01), Franklin
patent: 5142086 (1992-08-01), King, Jr. et al.

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