Method for preparing block polyphenylene ether-polycarbonates

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 68, 525 92, 525132, 525152, 525391, 525392, 525905, C08G 6548, C08L 6900, C08L 7112

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049736280

ABSTRACT:
Block polyphenylene ether-polycarbonate copolymers are prepared by the reaction of a salicylate-terminated polycarbonate with a polyphenylene ether in the presence of a polycarbonate-forming transesterification catalyst. The reaction may be conducted in solution or in the melt, typically at temperatures in the range of about 100.degree.-300.degree. C. The preferred catalysts are tetraarylborates, especially tetraalkylammonium tetraarylborates.

REFERENCES:
patent: 4323668 (1982-04-01), Brunelle
patent: 4374233 (1983-02-01), Loucks et al.
patent: 4377662 (1983-03-01), Loucks
patent: 4760118 (1988-07-01), White et al.

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