Method for preparing block copolymers of propylene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525323, C08F29708

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active

051752085

ABSTRACT:
An improved method for preparing block copolymers of propylene which comprises providing a polymerizer composed of at least two reaction vessels connected to one another, substantially homopolymerizing propylene in a first step and then copolymerizing ethylene and propylene in a second step in the presence of a stereoregular catalyst, characterized by carrying out the homopolymerization of propylene in the polymerizer composed of at least two reaction vessels connected to one another in series, then introducing the resulting polymer slurry into a countercurrent washing column and countercurrently washing the slurry with propylene, introducing the washed slurry withdrawn from the lower part of the washing column into a reaction vessel in the second step connected to the washing column and performing the polymerization of ethylene and propylene, of which ratio ranges from 15/85 to 95/5. According to this method, a block copolymer of propylene exhibiting excellent physical properties can be obtained efficiently.

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patent: 4692501 (1987-07-01), Mineshima et al.
patent: 4751265 (1988-06-01), Asanuma et al.

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