Method for preparing bisphenol A

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568722, 568724, 568728, C07C 396, C07C 3720

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active

050877674

ABSTRACT:
A method for preparing 2,2-bis(4-hydroxyphenyl)propane comprises reacting acetone and phenol in the presence of an acidic ion-exchange resin as a catalyst wherein the reaction of acetone and phenol is performed while removing a part of the water generated during the reaction from a mixed solution containing acetone and phenol by a pervaporation method. According to the method, the water generated through the reaction can rapidly be removed simultaneously with or alternatively to the reaction by a pervaporation operation and, therefore, the catalytic activity of the ion-exchange resin is not impaired at all. Moreover, any complicated operations associated with the dehydration are not required. Thus, the acidic ion-exchange resin catalyst can continuously be used over a long time period without any treatment for the regeneration thereof. Further, according to the method, bisphenol A can be economically prepared from acetone and phenol in a high conversion rate and high yield.

REFERENCES:
patent: 2572141 (1951-10-01), Harris
patent: 2884462 (1959-04-01), Henry
patent: 4777301 (1988-10-01), Olson
Patent Abstracts of Japan, vol. 10, No. 252 (C-369)(2308), 08/29/86; JP-A-6178741.

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