Method for preparing aromatic secondary amino compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564385, 564391, 564397, 564415, 562443, 562458, 549480, 549492, C07C20924

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active

055368786

ABSTRACT:
Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and (2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.

REFERENCES:
patent: 5344987 (1994-09-01), Immel et al.
patent: 5449829 (1995-09-01), Kusuda et al.

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