Method for preparing and identifying N-substitued 1,4-piperazine

Chemistry: molecular biology and microbiology – Measuring or testing process involving enzymes or... – Involving antigen-antibody binding – specific binding protein...

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436501, 436518, G01N 3353, G01N 33566, G01N 33543

Patent

active

058112413

ABSTRACT:
The invention provides a method of synthesizing N-substituted 1,4-piperazines and N-substituted 1,4-piperazinediones. The invention also provides a method for synthesing combinatorial libraries of piperazine derivatives which can be assayed for biological activity in pre-specified ligand binding or enzymatic activity screens.

REFERENCES:
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Bunin, B. A., et al., "A General and Expedient Method for the Solid-Phase Synthesis of 1,4-Benzodiazephine Derivatives," J. Am. Chem. Soc., 114, 10997-10998 (1992).
DeWitt, S. H., et al., "Diversomers: An Approach to Nonpeptide, Nonologomeric Chemical Diversity", Proc. Nat. Acad. Sci. USA, 90, 6909-6913 (Aug., 1993).
Gallop MA, et al, (1994) Applications of combinatorial technologies to drug discovery. 1. Background and peptide combinatorial libraries. J Med.Chem. 37:1233-1251.
Gordon DW, et al, (1995) Reductive alkylation on a solid phase: Synthesis of a piperazinedione combinatorial library. Bioorg.Med.Chem. 5:47-50.

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