Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters
Patent
1992-09-03
1993-10-26
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carbonate esters
568804, C07C 6996, C07C 3700
Patent
active
052568091
ABSTRACT:
4-Acetoxystyrene is reacted with a base in a solvent to form a salt of 4-hydroxystyrene via saponification. Alternatively, 4-hydroxystyrene is reacted with a base to form a salt of 4-hydroxystyrene. In the latter case, the 4-hydroxystyrene is prepared by the transesterification of 4-acetoxystyrene. Subsequently or simultaneously, the salt of 4-hydroxystyrene is reacted, preferably in situ. with di-tertiary-butyl-dicarbonate to form 4-tertiary-butoxycarbonyloxystyrene.
REFERENCES:
patent: 4491628 (1985-01-01), Ito et al.
patent: 5082965 (1992-01-01), Nader et al.
patent: 5087772 (1992-02-01), Sheehan
"Preparation of Cinylphenols and Isopropenylphenols", Corson et al., vol. 23, Apr. 1958, J. Org. Chem.
"Poly(p-tert-butoxycarbonyloxystyrene): A Convenient Precursor to p-Hydroxystyrene Resins", Frechet et al., Polymer, 1983, p. 995.
Kvakoyszky George
Rea James H.
Sheehan Michael T.
Smith Brad L.
Cassady Donald R.
Dees Jos,e G.
Ferrell Michael W.
Hoechst Celanese Corporation
Jones Dwayne C.
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