Method for preparing a pillared layered oxide material

Details Method for preparing a pillared layered oxide material Method for preparing a pillared layered oxide material

1992-05-04

1994-01-11

Breneman, R. Bruce

Catalyst, solid sorbent, or support therefor: product or process

Zeolite or clay, including gallium analogs

Clay

502242, 4233291, 4233282, B01J 2106

Patent

active

052781160

ABSTRACT:
There is provided a method for preparing a pillared layered material, designated MCM-36, with a characteristic X-ray diffraction pattern. Upon calcination of the swollen, non-pillared form of this material, the layers collapse and condense upon one another in a somewhat disordered fashion to form a non-swellable material. However, when the swollen layered material is intercalated with polymeric oxide pillars, the layer separation is maintained, even after calcination. Cerium-containing aluminum phosphate gel particles are used to pillar the layered material.

REFERENCES:
patent: 4439409 (1984-03-01), Puppe et al.
patent: 4859648 (1989-08-01), Landis et al.
patent: 4954325 (1990-09-01), Rubin et al.

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