Method for preparing a modified solid oxide

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502305, 502308, 502310, 502313, 502314, 502315, 502316, B01J 2316, B01J 2322, B01J 2324, B01J 2330

Patent

active

057803820

ABSTRACT:
There is provided a method for preparing an acidic solid comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this acidic solid is zirconia, modified with tungstate. This modified solid oxide may be used as a catalyst, for example, to isomerize C.sub.4 to C.sub.8 paraffins. The method for preparing this acidic solid involves contacting a hydrated oxide of a Group IVB metal under hydrothermal conditions, such as reflux conditions, prior to contact of the hydrated oxide with an aqueous solution comprising a source of an oxyanion of a Group VIB metal.

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patent: 5113034 (1992-05-01), Soled et al.
patent: 5283041 (1994-02-01), Nguyen et al.
Arata et al., "Synthesis of Solid Superacid of Tungsten Oxide Supported on Zirconia and Its Catalytic Action," Proceedings 9th International Congress on Catalysis, vol. 4, 1727-1734 (1988) no month available.
Hino, M. et al., "Synthesis of Solid Superacid of Tungsten Oxide Supported on Zirconia and its Catalytic Action for Reactions of Butane and Pentane," J. Chem., Soc., Chem. Commun. 1259-1260 (1988) no month available.

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