Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1997-10-09
2000-04-18
Wood, Elizabeth
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
5261249, 5261251, 526128, 526351, 502125, 502133, C08F 444, C08F11006, B01J 3100, B01J 3700
Patent
active
060516666
ABSTRACT:
A method for polymerizing at least one olefin by contacting at least one olefin with a polymerization catalyst and an organometallic compound containing a metal from group 1, 2, 12 or 13 of the Periodic System of Elements under effective polymerization conditions. The polymerization catalyst is obtained by contacting metallic magnesium with an aromatic halide, RX, under conditions effective to obtain a first reaction product and solid residual products. The first reaction product is then separated from the solid residual products. A silane compound containing an alkoxy or aryloxy group is added to the first reaction product between -20.degree. C. to 20.degree. C. to obtain a precipitate which is purified to obtain a second reaction product. Subsequently, the second reaction product is contacted with a halogenized titanium compound, such as titanium tetrachloride, to obtain a further reaction product. The polymerization catalyst is obtained by purifying the further reaction product. In the aromatic halide, R represents an aromatic group containing from 6 to 20 carbon atoms and X represents a halide.
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Bukatov Gennadii D.
Sergeev Sergei A.
Zakharov Vladimir A.
DSM N.V.
Pasterczyk J.
Wood Elizabeth
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