Method for preparation of poly(o-phenylenediamine) Nano-belt

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Nitrogen-containing reactant

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C528S490000, C524S779000, C524S785000

Reexamination Certificate

active

07101961

ABSTRACT:
The present invention provides a method for preparation of poly(o-phenylenediamine) nano-belt comprising mixing aqueous solutions of o-phenylenediamine and of oxidant in a mole ratio of 1:0.1–1 under stirring; standing for 0.5–2 hrs at room temperature; and obtaining poly(o-phenylenediamine) nano-belt. The method is suitable for large-scale production. In the absence of template and surfactant, aqueous solutions of o-phenylenediamine and of oxidant are mixed in a specified mole ratio and thus obtain a poly(o-phenylenediamine) nano-belt with length of several hundred micrometers, width of several hundred nanometers and thickness of tens nanometers. The method is simple, quick and suitable for large-scale manufacture. The poly(o-phenylenediamine) nano-belt thus prepared possesses excellent semiconductor properties and is one of the most promising conductive polymer materials.

REFERENCES:
patent: 2003/0113611 (2003-06-01), Abe et al.
patent: 2004/0265692 (2004-12-01), Long et al.
Sun, X. et al. (2004) “Large scale, templateless, surfactantless route to rapid synthesis of uniform poly(o-phenylenediamine) nanobelts”Chem. Commun., pp. 1182-1183.
Cai, Z. et al. (1991) “Molecular and supermolecular origins of enhanced electronic conductivity in template-synthesized polyheterocyclic fibrils. 1. supermolecular effects”Chem. Mater. 3:960-967.
Cai, Z. et al. (1989) “Electronically conductive poymer fibers with mesoscopic diameters show enhanced electronic conductivities”J. Am. Chem. Soc. 111:4138-4139.
Cepak, V. et al. (1999) “Preparation of polymeric micro- and nanostructures using a template-based deposition method”Chem. Mater. 11:1363-1367.
Jang J. et al. (2003) “Facile fabrication of polypyrrole nanotubes using reverse microemulsion polymerization”Chem. Commun. pp. 720-721.
Martin, C. et al. (1990) “Template synthesis of organic microtubules”J. Am. Chem. Soc. 112:8976-8977.
Ma{overscore (r)}tin, C. et al. (1993) “Template synthesis of electronically conductive polymers—a new route for achieving higher electronic conductivities”Synthetic Metals55-57: 1165-1170.
Martin, C. et al. (1991) “Template synthesis of polymeric and metal microtubules”Adv. Mater. 3:457-459.
Parthasarathy, R. et al. (1994) “Synthesis of polymeric microcapsule arrays and their use for enzyme immobilization”Nature369:298-301.
Penner R. et al. (1986) “Controlling the morphology of electronically conductive polymers”Journal of the Electronic Society, pp. 2206-2207.
Van Dyke, L. et al. (1990) “Electrochemical investigations of electronically conductive polymers. 4. controlling the supermolecular structure allows charge transport rates to be enhanced”Langmuir6:1118-1123.
Wei, Z. et al. (2002) “Formation mechanisms of self-assembled polyaniline micro-nanotubes”Langmuir18:917-921.
Wu, C.-G. et al. (1994) “Conducting polyaniline filaments in a mesoporous channel host”Science264:1757-1759.
Wu, C.G. et al. (1994) “Polyaniline wires in oxidant-containing mesoporous channel hosts”Chem. Mater. 6:1109-1112.
Zhang, F. et al. (2002) “Conducting polymer nanowires and nanodots made with soft lithography”Nano Letters2:1373-1377.
Zhang, Z. et al. (2002) “Nanostructures of polyaniline doped with inorganic acids”Macromolecules35:5937-5942.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method for preparation of poly(o-phenylenediamine) Nano-belt does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method for preparation of poly(o-phenylenediamine) Nano-belt, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method for preparation of poly(o-phenylenediamine) Nano-belt will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3531846

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.