Method for preparation of pharmaceutical-grade dithiocarbamate

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – N-c doai

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564 74, 564 75, A01N 4710

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active

061243493

ABSTRACT:
The present invention provides methods for producing pharmaceutical-grade particulate dithiocarbamates from secondary amines by vigorously contacting at least one secondary amine and a pharmaceutically acceptable diluent that is a solvent for the carbon disulfide, but not for the secondary amine in an inert gas atmosphere, cooling the mixture so as to precipitate the dithiocarbamate therefrom, and separating the precipitated dithiocarbamate from the cooled mixture. The preferred solvent contains absolute ethanol. In alternative embodiments, the invention further provides methods for purifying a dithiocarbamate to obtain a pharmaceutical-grade dithiocarbamate particulate from a dithiocarbamate feed and methods for producing a sterile pharmaceutical-grade dithiocarbamate from a dithiocarbamate feed.

REFERENCES:
patent: 5741815 (1998-04-01), Lai
patent: 5747532 (1998-05-01), Lai
patent: 5756540 (1998-05-01), Lai
patent: 5847004 (1998-12-01), Lai
Lee et al., "Sugar-Linked Dithiocarbamates as Modulators of Metabolic and Genotoxic Properties of N-Nitroso Compounds," J. Med. Chem., 37:3154-3162 (1994).
Shinobu, et al., "Sodium N-Methyl-D-glucamine Dithiocarbamate and Cadmium Intoxication," Acta Pharmacol. et Toxicol., 54:189-194 (1984).
Singh et al., "Molecular-Modeling Design of Cadmium-Mobilizing Agents: A Novel Biscarbodithioate," Chem. Res. Toxicol., 7:614-620 (1994).

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