Method for preparation of cross-condensed compound between...

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

Reexamination Certificate

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C556S465000, C556S466000

Reexamination Certificate

active

08003815

ABSTRACT:
The present invention provides a method of preparing a cross-condensed compound of an amino-acid derivative and (aminoalkyl)trialkoxysilane using microwave, including: irradiating and heating an amino-acid derivative and (aminoalkyl)trialkoxysilane in a microwave reactor to obtain a reaction product (step 1); and refining the reaction product obtained in the step 1 by removing an unreacted solid material from the reaction product and then leaving the reaction product at room temperature under vacuum to remove excess (aminoalkyl)trialkoxysilane therefrom (step 2). According to the method, since a cross-condensation reaction is performed using microwave, unlike a conventional condensation reaction, economic efficiency is increased due to no catalyst, short reaction time and no solvent. Further, the yield and selectivity of products is increased, and the condensation reaction can be environment-friendly performed because a solvent which can badly influence the environment may not be used.

REFERENCES:
patent: 5883349 (1999-03-01), Kingston
patent: 6437167 (2002-08-01), Sunjic et al.
patent: 2005/0143592 (2005-06-01), Auner
patent: 2007/0232809 (2007-10-01), Kim et al.
Goretzki et al., {Green Polymer Chemistry: Microwave-Assisted Single-Step Synthesis of Various (Meth) Acrylamides and Poly (Meth) Acrylamides Directly from (Meth) Acrylic Acid and Amines, Macromol. Rapid Commun. 2004, vol. 25, pp. 513-516}.
Goretzki, C. et al., “Green Polymer Chemistry: Microwave-Assisted Single-Step Synthesis of Various (Meth) Acrylamides and Poly (Meth) Acrylamides Directly from (Meth) Acrylic Acid and Amines.” Macromol. Rapid Commun. 2004, vol. 25, pp. 513-516, Wiley-VCH Verlag GmbH & Co.

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