Method for preparation of copolyorganosiloxanecarbonates of...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C528S025000, C528S196000

Reexamination Certificate

active

06870013

ABSTRACT:
Copolyorganosiloxanecarbonates are prepared by first preparing an oligomeric aromatic polycarbonate, such as an oligomeric bisphenol A polycarbonate, in the presence of a tertiary amine as the only catalyst species; contacting the oligomeric polycarbonate mixture with a polyorganosiloxane bis(aryl)chloroformate, such as the bischloroformate of hydroxy-terminated eugenol polydimethylsiloxane; and introducing phosgene and/or chain termination agent either continuously or in stages. A feature of the process is the presence of dihydroxyaromatic compound in only one charge, at the beginning. The products have excellent physical properties, including transparency.

REFERENCES:
patent: 5530083 (1996-06-01), Phelps et al.
patent: 5616674 (1997-04-01), Michel et al.
patent: 6492481 (2002-12-01), Davis et al.

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