Method for preparation of carborane anions

Organic compounds -- part of the class 532-570 series – Organic compounds – Boron containing

Reexamination Certificate

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C568S004000

Reexamination Certificate

active

10472329

ABSTRACT:
This invention relates to an improved method for making unsubstituted carborane anions and monosubstituted carborane anions of formula: (R—CBn—Hm′)−where n is an integer ranging from 5 to about 11 and m′ is an integer ranging from 5 to 16 where the relative values of n and m′ depend upon the exact structure of the carborane and the presence of a non-hydrogen substituent. m as used herein is an integer ranging from 5 to 16. When R is hydrogen the anion is unsubstituted. When R is a halogen, a phenyl, a substituted phenyl group, such as fluorophenyl group, or any other substituent, the carborane is substituted. The method is particularly useful for preparation of twelve-vertex carborane anions R—CB11H11−, where R is a defined above, and is specifically useful for preparation of the unsubstituted carborane CB11H12-??, where R is H.

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K. Nestor et al.,Ten-vertex monocarbaborane chemistry. 17. A convenient new preparation of[closo-1-CB9H10]-anion and the crystal and molecular structure of[(η5-C5Me5)Ir22 CI3]+[closo-1-CB99H10]-, Collect. Czech. Chem. Commun. 57(6):1262-1268, 1992.
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