Method for preparation of allylsilanes

Details Method for preparation of allylsilanes Method for preparation of allylsilanes

1996-03-28

1997-05-13

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 708

Patent

active

056294395

ABSTRACT:
A method for the preparation of allylsilanes. The method comprises contacting magnesium metal with a mixture comprising diethylene glycol dibutyl ether, allyl halide, and a halosilane at a temperature within a range of about 5.degree. C. to 20.degree. C. The method provides a high yield of allylsilane product that is easily recoverable and also provides for high ratios of allylsilane to hexadiene by-product.

REFERENCES:
patent: 5068386 (1991-11-01), Shirahata
patent: 5294727 (1994-03-01), Kubota et al.
patent: 5358670 (1994-10-01), Turnbull et al.
Organometallic Compounds, Coates et al., vol. 1 76-103, (1967), Methuen & Co. LTD, London, UK.
Encyclopedia of Chem Technology, Kirk & Othmer, vol. 10, 721-734 (1966), The Interscience Encyclopedia, Inc. NY, NY.
Grignard Reactions of Nonmetallic Substances, Kharash et al, Printice-Hall, Inc. NY, 1954, 1306-1331.
Organic Synthesis, Turk et al., vol. 27, 7-8, 1947.

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