Method for preferential hydrogenation of terminal methylene grou

Details Method for preferential hydrogenation of terminal methylene grou Method for preferential hydrogenation of terminal methylene grou

1980-12-16

1982-04-27

Niebling, John F.

Chemistry of hydrocarbon compounds

Adding hydrogen to unsaturated bond of hydrocarbon, i.e.,...

Hydrocarbon is aromatic

585266, 585275, 585277, 568840, 560265, C07C 710

Patent

active

043272355

ABSTRACT:
In an organic compound having a methlene group attached to a tertiary carbon atom thereof, preferential hydrogenation of the methylene group of the compound is effected by bringing hydrogen into contact with the compound in the presence of a nickel boride colloid.

REFERENCES:
Brown, J. Org. Chem., vol. 35, No. 6, 1970.
Koji et al., Chem. Absts., vol. 82: 155535v.

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