Method for polymerizing macrocyclic poly(alkylene dicarboxylate)

Chemistry of hydrocarbon compounds – Compound or reaction product mixture

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502100, 528494, 528272, C07C 1300

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active

055279767

ABSTRACT:
Macrocyclic polyester oligomers are converted to linear polyesters by contact at a temperature of about 160.degree.-300.degree. C. with a cyclic titanium catalyst such as di-(1-butyl)-2,2-dimethylpropane-1,3-dioxytitanate, bis(2,2-dimethyl-1,3-propylene)titanate or 1-(1-butoxy)-4-methyl-2,6,7-trioxa-1-titanabicyclo[2.2.2]octane. Such catalysts have high activity and produce linear or branched polyesters of very high molecular weight.

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