Method for plating conductive plastics

Chemistry: electrical and wave energy – Processes and products

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204 30, 427259, 427290, 427306, C25D 556, B05D 310, B05D 312

Patent

active

045928088

ABSTRACT:
A method for plating conductive plastics. The area to be plated is abrasively blasted as necessary to produce suitable mechanical bonding sites. The area is cleaned with a hot alkaline cleaning solution that will not appreciably attack the plastic. The area is sensitized to provide a base for firm adhesion of the metal onto the plastic. Sensitizing a graphite-reinforced epoxy composite preferably includes flowing a dilute solution of hydrochloric acid over the area, flowing a palladium chloride catalyst, rinsing the area, flowing a stannous accelerator, and rinsing the area again. Striking is then carried out by flowing an electroless plating solution over the area to provide a preliminary deposit of metal. The electroless solution may be either copper or nickel. The flowing of each solution is done at a very low velocity to ensure effective and even action on the entire area. Following striking, a plating buildup is provided as required. The plating buildup may be accomplished by continuing the electroless plating process, immersing the area and carrying out electrolytic plating, or brush plating the area. Whatever plating method is chosen, steps must be taken to protect against overheating of the conductive plastic.

REFERENCES:
patent: 3093509 (1963-06-01), Wein
patent: 3438226 (1969-04-01), Dalpiaz
patent: 3671285 (1972-05-01), Prescott
patent: 4038042 (1977-07-01), Adelman
patent: 4159934 (1979-07-01), Kadija
patent: 4264646 (1981-04-01), Thornburg et al.
patent: 4353933 (1982-10-01), Araki et al.
"ABS Joins Plastics That Can Be Plated", from the Mar. 1963 issue of C & EN, pp. 48-49.

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