Method for oligomerizing olefins

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

Reexamination Certificate

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C585S527000, C585S532000

Reexamination Certificate

active

10509871

ABSTRACT:
Olefins are oligomerized by contacting an olefin with a catalyst system that is comprised of a) at least one transition metal complex that is complexed with a polydentate complexing ligand and b) an alkylaluminoxane, each component being present in such amounts that the molar ratio of aluminum transition metal is greater than 10, wherein at least part of the amount of the transition metal complex is added continuously or in portions during the oligomerization.

REFERENCES:
patent: 30 07 725 (1981-09-01), None
patent: 199 43 544 (2001-03-01), None
patent: 0 531 174 (1993-03-01), None
patent: 0 537 609 (1993-04-01), None
Tani, Kazuhide et al. “Preparation of .alpha.-olefin polymers by the use of vanadium or chromium complex catalysts”, STN Caplus, vol. 129, No. 18, XP002139725, English abstract only 1998.
Koide, Yoshihiro et al. “Alumoxanes as Cocatalysts in the Palladium-Catalyzed Copolymerization of Carbon Monoxide and Ethylene: Genesis of a Structure-Activity Relationship”, Organometallics, vol. 15, pp. 2213-2226 1996.
Barron, Andrew R. “A New Understanding of the Co-Catalytic Activity of Alumoxanes: The Opening of a Black Box!”, Macromol. Symp., vol. 97, pp. 15-25 1995.
Gladysz, J.A. “Frontiers in Metal-Catalyzed Polymerization: Designer Metallocenes, Designs on New Monomers, Demystifying MAO, Metathesis Deshabille”, Chemical Reviews, vol. 100, No. 4, pp. 1167-1168 2000.
Ruether, Thomas et al. “Novel Chromium(III) Complexes Containing Imidazole-Based Chelate Ligands with Varying Donor Sets: Synthesis and Reactivity”, Organometallics, vol. 20, pp. 1247-1250 2001.
Doehring, Amo et al. “Donor-Ligand-Substituted Cyclopentadienylchromium(III) Complexes: A New Class of Alkene Polymerization Catalyst. 2. Phosphinoalkyl-Subsituted Systems”, Organometallics, vol. 20, pp. 2234-2245 2001.
Deckers, Patrick J.W. et al. “Switching a Catalyst System from Ethene Polymerization to Ethene Trimerization with a Hemilabile Ancillary Ligand”, Angew. Chem., vol. 113, No. 13, pp. 2584-2587 2001.

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