Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Patent
1983-01-10
1985-04-30
Griffin, Ronald W.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
106 35, 26099811, 424147, 433228, 523114, 523116, 548433, A10N 102, A65K 500, C09K 300
Patent
active
045145270
ABSTRACT:
Materials and methods for improving the adhesion of composite materials and resins to dentin, enamel and other substrates are disclosed. Preferably, the substrate is treated with an aqueous solution of at least one acidic salt containing a polyvalent cation which preferably is capable of changing valence by unit steps (univalent changes) and which can bind to dentin or enamel surface sites, and at least one anion which preferably forms a relatively water-insoluble precipitate or precipitates with calcium, and which contains at least one carboxyl group and preferably two or more carboxyl groups. The resultant surface is then treated with a solvent containing at least one compound selected from the group consisting of (1) the adduct of N(p-tolyl)glycine and glycidyl methacrylate ("NTG-GMA"), and (2) the addition reaction product of N-phenylglycine and glycidyl methacrylate ("NPG-GMA"). Finally, a solution is applied which contains at least one compound selected from the group consisting of (1) the addition reaction product of pyromellitic acid dianhydride and 2-hydroxyethyl methacrylate ("PMDM"), (2) the addition reaction product of 3,3',4,4'-benzophenonetetracarboxylic dianhydride and 2-hydroxyethyl methacrylate ("BTDA-HEMA"), and (3) 4-methacryloxyethyltrimellitic anhydride ("4-META"). Alternative embodiments are also set forth.
REFERENCES:
patent: 3200142 (1965-08-01), Bowen
patent: 3635889 (1972-01-01), Bowen
patent: 3785832 (1974-01-01), Bowen
patent: 4001483 (1977-01-01), Lee et al.
patent: 4148988 (1979-04-01), Masuhara et al.
patent: 4155890 (1979-05-01), Hofacker-Freifrau
patent: 4188317 (1980-02-01), Temin
patent: 4235633 (1980-11-01), Tomioka et al.
patent: 4251565 (1981-02-01), Bowen
patent: 4302376 (1981-11-01), Walkowiak et al.
patent: 4373035 (1983-02-01), Bowen
patent: 4433959 (1984-02-01), Faunce
Chemical Abstracts, vol. 86, No. 16, Apr. 18, 1977, p. 303, Abstract 86:111205r.
Chemical Abstracts, vol. 90, No. 8, Feb. 19, 1979, pp. 394-395, Abstract 90:61270t.
Chemical Abstracts, vol. 96, No. 16, Apr. 19, 1982, p. 463, Abstract 96:129756n.
Palit, S. R. and Koner, R. S., "Permanganate-Oxalic Acid as a Redox Initiator in Aqueous Media," 57 J. Polymer Sci., 609-615, (1962).
Lal et al., "New Polymerization Catalysts for Methyl Methacrylate," 24 J. Polym. Sci., 75-84, (1957).
Uehara, "Polymerization of Methyl Methacrylate Initiated by a Combined Action of Trichloroacetic Acid and Dimethylaniline," 31 Bull. Chem. Soc. Jap., 685-687, (1958).
Hrabak et al., "The Initiation of Polymerization of Unsaturated Tertiary Amines with Carboxylic Acids," 182 Macromol. Chem., 1595-1603, (1981).
Bowen, R. L., "Adhesive Bonding of Various Materials to Hard Tooth Tissues. I. Method of Determining Bond Strength," 44 J. Dent. Res., 690-695, (1965).
Bowen, R. L., "Investigation of the Surfaces of Hard Tooth Tissues by a Surface Activity Test," in Phillips, R., & Ryge, G. (eds.): Proceedings of the Workshop on Adhesive Restoration Dental Materials 177-191 at Indiana University, Sep. 28-29, 1961, Spencer, Indiana: Owen Litho Service.
Bowen, R. L., "Development of an Adhesive Restorative Material," in Adhesive Restorative Dental Materials II, 225-231, University of Virginia Workshop, Public Health Service Publication No. 1494, (Washington, D.C.: U.S. Government Printing Office, 1966).
Sax, N. I., Dangerous Properties of Industrial Materials, 715 (1957), Reinhold Publishing Corporation, New York, N.Y.
Dwyer, F. & Mellor, D., Chelating Agents and Metal Chelates, 311 (1964), Academic Press, New York, N.Y.
Bowen, R. L., "Adhesive Bonding of Various Materials to Hard Tooth Tissues. V. The Effect of a Surface-Active Comonomer on Adhesion to Diverse Substrates," 44 J. Dent. Res., 1369-1373, (1965).
Plueddemann, E., "Interfaces in Polymer Matrix Composites," in Composite Materials, vol. 6, (1974), pp. 173-216, published by Academic Press, New York, N.Y.
Jedrychowski et al., "Influence of a Ferric Chloride Mordant Solution on Resin-Dentin Retention," 60 J. Dent. Res., 134-138, (1981).
Bowen, R. L., "Adhesive Bonding of Various Materials to Hard Tooth Tissues. II. Bonding to Dentin Promoted by a Surface-Active Comonomer," 44 J. Dent. Res., 895-902, (1965).
Bowen, R. L., "Adhesive Bonding of Various Materials to Hard Tooth Tissues. III. Bonding to Dentin Improved by Pretreatment and the Use of a Surface-Active Comonomer," 44 J. Dent. Res., 903-905, (1965).
Bowen, R. L., "Adhesive Bonding of Various Materials to Hard Tooth Tissues. IV. Bonding to Dentin, Enamel, and Fluorapatite Improved by the Use of a Surface-Active Comonomer," 44 J. Dent. Res., 906-911, (1965).
Bowen, R. L., "Adhesive Bonding of Various Materia
American Dental Association - Health Foundation
Griffin Ronald W.
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