Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iib metal
Patent
1989-08-10
1991-02-12
Rosenberg, Peter D.
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Group iib metal
423 70, B01D 1100
Patent
active
049922483
ABSTRACT:
A method for neutralizing a sulfuric acid solution containing predominantly Zn ion, comprising adding, to the sulfuric acid solution, at least one compound selected from the group of chlorine-containing compounds of Na ion, K ion, Mg ion, Ca ion, and NH.sub.4 ion in an amount at least chemically equivalent to SO.sub.4 ion contained; and then bringing the sulfuric acid solution into contact with an organic solvent composed of one or more species selected from the group of oxygen-containing organic solvents and alkylamine organic solvents to extract Zn ion from the sulfuric acid solution as a chloride complex to the organic solvent. The sulfuric acid solution after extraction of Zn ion is further treated by addition of an oxidizing agent or by an electrochemical means to convert Fe.sup.2+ into to Fe.sup.3+ ion and is brought into contact with a second organic solvent B composed of one or more species selected from the group of oxygen-containing organic solvents and alkylamine organic solvents to extract Fe ion from the sulfuric acid solution as a second chloride complex to the second orgaic solvent B.
REFERENCES:
patent: 3067010 (1962-12-01), Long et al.
patent: 3104950 (1963-09-01), Ellis
patent: 3795727 (1974-03-01), Yamamura et al.
Sei Renpei
Watanabe Morio
Rosenberg Peter D.
Solex Corporation of Japan
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