Method for manufacturing pyridine and pyridine derivatives from

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546251, 546304, C07D21312

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active

045888159

ABSTRACT:
The preparation of pyridine and pyridine derivatives from alkynes and cyano compounds including HCN is disclosed. The process can be carried out in the presence of a cobalt or rhodium catalyst having at least one ligand with one or more boron atoms. Certain new cobalt or rhodium catalysts containing such ligand are also disclosed. Also disclosed is a process for the formation of 2-aminopyridine by contacting acetylene with cyanamide such as in the presence of a cobalt or rhodium catalyst which has at least one ligand with one or more boron atoms.

REFERENCES:
patent: 4006149 (1977-02-01), Bonnemann
Bonnemann et al., Chem. Abstracts, vol. 81, No. 19, Abst. No. 120,396c, Nov. 11, 1974.
Clement, Chem. Abstracts, vol. 81, No. 21, Abst. No. 135,962h, Nov. 25, 1974.
Bonnemann et al., Chem. Abstracts, vol. 84, No. 5, Abst. No. 30,909e, Feb. 2, 1976.
Bonnemann et al., Chem. Abstracts, vol. 93, No. 9, Abst. No. 95,136f, Sep. 1, 1980.
Yasuo et al., Chem. Abstracts, vol. 85, No. 5, Abst. No. 32,779g, Aug. 2, 1976.

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