Method for manufacturing 3-amino-2-cyclohexene-1-one, and a nove

Details Method for manufacturing 3-amino-2-cyclohexene-1-one, and a nove Method for manufacturing 3-amino-2-cyclohexene-1-one, and a nove

1992-08-17

1993-12-07

Robinson, Allen J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

C07C24902

Patent

active

052685080

ABSTRACT:
A method of manufacturing 3-amino-2-cyclohexene-1-one by hydrogenating m-phenylenediamene to produce a novel intermediate salt of 3-amino-2-cyclohexene-1-imine followed by hydrolysis to produce 3-amino-2-cyclohexene-1-one. The novel intermediate 3-amino-2-cyclohexene-1-imine has also be isolated.

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patent: 3975285 (1976-08-01), Ohnishi et al.
Murahashi et al., "Catalytic Alkyl Group Exchange, etc." J. Am. Chem. Soc. (1983), 105, 5002-5011.
Solomons, T., "Organic Chemistry", 2nd Ed., John Wiley and Sons, New York, 1980.
Journal of American Chemical Society, 108, 862 (1986).

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