Method for making radiation curable silicon containing polyacryl

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

524100, 524189, 524237, 524248, 524259, 524475, 524476, 524482, 524806, 524860, 524866, 526258, 526265, 526293, 526294, 526295, 526311, 526338, 5263403, C08K 53432, C08L 4304

Patent

active

054687896

ABSTRACT:
A method is provided for making curable silicon containing acrylate silicone hardcoat compositions which employ an anaerobic gelation inhibitor such as galvinoxyl. Devolatilizing of an aqueous/organic solvent mixture from the silicon containing acrylate hardcoat formulation is conducted in an inert atmosphere. Acrylate hardcoat compositions imparting improved weathering resistance to thermoplastic substrates also are provided.

REFERENCES:
patent: 3258477 (1966-06-01), Plueddemann et al.
patent: 4021310 (1977-05-01), Shimizu et al.
patent: 4385153 (1983-05-01), Ritter
patent: 4455205 (1985-06-01), Olson et al.
patent: 4491508 (1985-01-01), Olson
patent: 4528324 (1985-07-01), Chung et al.
patent: 4709067 (1987-11-01), Chu et al.
patent: 5242719 (1993-09-01), Medford et al.
patent: 5258225 (1993-11-01), Katsamberis
patent: 5271968 (1993-12-01), Coyle et al.
patent: 5312871 (1994-05-01), Mardare et al.
E. G. Janzen, Spin Trapping, Chem. Eng. News 43, 50 (Sep. 27, 1965), Amer. Chem. Soc. (pp. 31-40).
I. H. Leaver et al., E.S.R. of Nitroxide Radicals, Aust. J. Chem. 1969, (pp. 1891-1900).
J. C. Bevington and N. A. Ghanem, The Mechanisms of Inhibition and Retardation in Radical Polymerizations. Part III, The Use of a Stable Free Radical as an Inhibitor J. of Polymer Science, 1956, (pp. 3506, 3507 and 3509).
R. C. Lamb et al., Organic Peroxides, III. The Behavior of Cyclohexaneformyl Peroxide in the Presence of Excess Stable Radicals. The Simultaneous Determination of Kinetics and Free Radical Efficiencies in the Thermal Decompositions of Free Radical Initiators, J. Phys. Chem. 1963, (pp. 914-917).
C. Anderson Evans, Spin Trapping, Aldrichimica Acta. vol. 12, No. 2, 1979 (pp. 23, 25 26-29).
P. D. Bartlett, Galvinoxyl (2,6-Di-tert-butyl-a-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadiene-1-ylidene )-p-tolyloxy) As a Scavenger of Shorter-lived Free Radicals, J. Chem. Soc. 1962 (99. 2596-2601).
J. F. Areizaga et al., Galvinoxyl As Scavenger in the Radical Polymerization of Styrene Initiated by AIBN, Makromol. Chem. Macromol. Symp. 20/21, 1988 (pp. 77, 79-82).
S. F. Nelsen, Azocumene. I. Preparation and Decomposition of Azocumene. Unsymmetrical Coupling Products of the Cumyl Radical, J. Am. Chem. Soc., 1965, (pp. 137-142).
L. N. Lewis et al., Ultraviolet-Curable, Abrasion-Resistant, and Weatherable Coatings with Improved Adhesion, J. of Applied Polymer Science, vol. 42, 1991, (pp. 1551-1556).
M. Stickler, Experimental Techniques in Free Radical Polymerization Kinetics, Makromol Chem. Macromol. Symp. 10/11, 1987, (pp. 17-69).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method for making radiation curable silicon containing polyacryl does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method for making radiation curable silicon containing polyacryl, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method for making radiation curable silicon containing polyacryl will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1137631

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.