Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Patent
1989-10-31
1991-02-12
Prescott, Arthur C.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
556 1, C07F 990
Patent
active
049925717
ABSTRACT:
A one pot method is provided for preparing an (octyloxyphenyl) phenyliodonium tosylate and the corresponding hexafluorometalloid salt. n-Octylphenyl ether is initially prepared using a halooctane and phenol in the presence of a phase transfer catalyst followed by the addition of iodobenzene, a peracid, and p-toluene sulfonic acid. The resulting (octyloxyphenyl)phenyl iodonium tosylate can be directly metathesized after an optional treatment step with an alkali metal hexafluoroantimonate salt. The (octyloxyphenyl)phenyl iodonium hexafluorometalloid salt can be used as a photoinitiator for UV curable organic materials such as epoxy resins.
REFERENCES:
patent: 4058400 (1977-11-01), Crivello
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patent: 4399071 (1983-08-01), Crivello et al.
patent: 4537725 (1985-08-01), Irving
patent: 4933377 (1990-06-01), Saeva et al.
Crivello James V.
Fukuyama James M.
Lee Julia L.
Davis Jr. James C.
General Electric Company
Pittman William H.
Prescott Arthur C.
Teoli William A.
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