Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1988-10-20
1993-06-08
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
560233, C07C 5114
Patent
active
052181456
ABSTRACT:
In the manufacture of isobutyric acid or its precursors or esters by the Koch synthesis from propylene, carbon monoxide, and, optionally, water or an alcohol in liquid hydrogen fluoride, the reaction mixture is maintained at a constant reaction temperature in a heat exchanger using an addition product of at least two of the aforementioned materials, preferably isopropanol, as a coolant.
REFERENCES:
patent: 2154795 (1939-04-01), Westenberg
patent: 4452999 (1984-06-01), Besecke et al.
patent: 4590293 (1986-05-01), Pascoe
patent: 4647696 (1987-03-01), Besecke et al.
patent: 4791227 (1988-12-01), Neumann et al.
New Synthesis with Carbon Monoxide, edited by J. Falbe, Springer-Verlag, Berlin, 1980 pp. 372-374.
Ruppert Wolfgang
Siegert Hermann-Josef
Barts Samuel
Dees Jos,e G.
Rohm GmbH
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