Method for making isobutyric acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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560233, C07C 5114

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active

052181456

ABSTRACT:
In the manufacture of isobutyric acid or its precursors or esters by the Koch synthesis from propylene, carbon monoxide, and, optionally, water or an alcohol in liquid hydrogen fluoride, the reaction mixture is maintained at a constant reaction temperature in a heat exchanger using an addition product of at least two of the aforementioned materials, preferably isopropanol, as a coolant.

REFERENCES:
patent: 2154795 (1939-04-01), Westenberg
patent: 4452999 (1984-06-01), Besecke et al.
patent: 4590293 (1986-05-01), Pascoe
patent: 4647696 (1987-03-01), Besecke et al.
patent: 4791227 (1988-12-01), Neumann et al.
New Synthesis with Carbon Monoxide, edited by J. Falbe, Springer-Verlag, Berlin, 1980 pp. 372-374.

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