Method for making germanium-silicate gel glass and articles

Compositions: ceramic – Ceramic compositions – Glass compositions – compositions containing glass other than...

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65 17, 501 37, 501 42, 501 54, 501 55, 501 73, C03C 304, C03C 312

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044775806

ABSTRACT:
Optical components using a germania-silica glass are made by a gel technique. Tetra pentyloxygermane and a silicon alkoxide are hydrolyzed to form a gel, which is subsequently dried. Optical components, including optical fibers and devices, can be made using glass prepared by this technique.

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patent: 4220461 (1980-09-01), Samanta
patent: 4278632 (1981-07-01), Yoldas
patent: 4323381 (1982-04-01), Matsuyama et al.
Schlichting, J. et al.--"GeO.sub.2 /SiO.sub.2 -Glasses from Gels to Increase the Oxidation Resistance of Porous Silicon Containing Ceramics," J. of Non-Crystalline Solids, 48 (1982), pp. 185-194.
Sakka, S.--"Gel Method for Making Glass" Treatise on Materials Science and Technology, 22 (1982), pp. 129-167.
Johnson, O. H. et al., "Tetraalkoxygermanes", J. Am. Chem. Soc. 75 (1953), pp. 718-720.
Nogami, M. et al., "Glass Formation Through Hydrolysis of Si(OC.sub.2 H.sub.5).sub.4 With NH.sub.4 OH and HCl Solution"--J. of Non-Crystalline Solids, 37 (1980), pp. 191-201.
Susa, K. et al., "New Optical Fibre Fabrication Method", Electronics Letters, 18 (12) (1982), pp. 499-500.

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