Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Reexamination Certificate
2008-12-31
2011-11-15
Puttlitz, Karl J (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
C560S133000, C564S048000, C564S063000
Reexamination Certificate
active
08058469
ABSTRACT:
The present invention provides methods of forming carbamates, ureas, and isocyanates. In certain embodiments these methods include the step of reacting an amine with an ester-substituted diaryl carbonate to form an activated carbamate which can be further derivitized to form non-activated carbamate or a urea. The urea or carbamate can be subjected to a pyrolysis reaction to form isocyanate.
REFERENCES:
patent: 3681457 (1972-08-01), Babad
patent: 3723432 (1973-03-01), Ott
patent: 3759920 (1973-09-01), Linder et al.
patent: 3763217 (1973-10-01), Brill et al.
patent: 3937705 (1976-02-01), Hardtmann
patent: 3937708 (1976-02-01), Mentrup et al.
patent: 4086246 (1978-04-01), Toth et al.
patent: 4272441 (1981-06-01), Keay et al.
patent: 4323668 (1982-04-01), Brunelle
patent: 4387223 (1983-06-01), Yamamoto et al.
patent: 4474978 (1984-10-01), Drent et al.
patent: 4537960 (1985-08-01), Merger et al.
patent: 4550188 (1985-10-01), Frulla et al.
patent: 4551169 (1985-11-01), Takematsu et al.
patent: 4567287 (1986-01-01), Frulla et al.
patent: 4725980 (1988-02-01), Barcelo et al.
patent: 5463109 (1995-10-01), Nishihira et al.
patent: 5962721 (1999-10-01), Kim et al.
patent: 6133473 (2000-10-01), Berrier
patent: 6420512 (2002-07-01), McCloskey et al.
patent: 6506871 (2003-01-01), Silvi et al.
patent: 6518391 (2003-02-01), McCloskey et al.
patent: 6548623 (2003-04-01), Brunelle et al.
patent: 6790929 (2004-09-01), Silvi et al.
patent: 2003/0100598 (2003-05-01), Mourelle Mancini et al.
patent: 2003/0139529 (2003-07-01), O'Neil et al.
patent: 2003/0149223 (2003-08-01), McCloskey et al.
patent: 2005/0222450 (2005-10-01), Gupte et al.
patent: 2007/0270605 (2007-11-01), Srinivas et al.
patent: 2007/0282091 (2007-12-01), Buckley et al.
patent: 2008/0287640 (2008-11-01), Belfadhel et al.
patent: 0065025 (1982-11-01), None
patent: 0065026 (1982-11-01), None
patent: 0083764 (1983-07-01), None
patent: 0086281 (1983-08-01), None
patent: 0190466 (1986-08-01), None
patent: 0296686 (1988-12-01), None
patent: 1491535 (2004-12-01), None
patent: 9-143144 (1997-06-01), None
patent: 9855450 (1998-12-01), None
patent: 2005009978 (2005-02-01), None
patent: 2006000845 (2006-01-01), None
patent: 2009155592 (2009-12-01), None
Evans et al., Asymmetric Synthesis of the Enkephalinase Inhibitor Thiorphan, J. Org. Chem,, 1985, pp. 1830-1835, vol. 50(11).
Fujita et al., Synthesis of 1,3-dialkylurea from ethylene carbonate and amine using calcium oxide, Journal of Molecular Catalysis A: Chemical, Apr. 6, 2005, pp. 43-48, vol. 230.
Majer et al., A Safe and Efficient Method for Preparation of N,N'-Unsymmetrically Disubstituted Ureas Utilizing Triphosgene, The Journal of Organic Chemistry, 1994, pp. 1937-1938, vol. 59(7).
Peng et al., N,N'-phosgenation with triphosgene in the synthesis of direct dyes containing the ureylene group, Dyes and Pigments, Dec. 1996, pp. 193-198, vol. 32, No. 4.
Vauthey et al., An environmentally benign access to carbamates and ureas, Tetrahedron Letters, Aug. 12, 2000, pp. 6347-6350, vol. 41, Issue 33.
Curini et al., Carbamate synthesis from amines and dimethyl carbonate under ytterbium triflate catalysis, Tetrahedron Letters, Jul. 8, 2002, pp. 4895-4897, vol. 43.
Belfadhel Hatem Abdallah
Brack Hans-Peter
Godoy-Lopez Ricardo
Willemse Dennis James Patrick Maria
Cantor & Colburn LLP
Puttlitz Karl J
Sabic Innovative Plastics IP B.V.
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