Method for making block siloxane copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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528 22, 528 32, 528 33, 528 37, C08G 6700, C08G 7708, C08G 7732

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043485049

ABSTRACT:
A method for synthesizing block polysiloxane copolymers. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

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West, et al., "New Anionic Rearrangements VIII. 1,4-Anionic Rearrangement of Silylethylenediamines", J. Amer. Chem. Soc. 90:3, pp. 727-731 (1968).

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