Method for inhibiting or controlling inorganic scale...

Wells – Processes – Material placed in pores of formation to treat resident...

Reexamination Certificate

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C166S307000, C166S308200, C166S310000, C166S312000, C507S222000, C507S224000, C507S225000, C507S229000, C507S242000, C507S243000, C507S244000, C507S927000

Reexamination Certificate

active

07398824

ABSTRACT:
A formulation containing a copolymer derived from a cationic monomer effectively inhibits and controls the formation of inorganic scales. Suitable copolymers include those comprising an acrylamide unit and a quaternary ammonium salt group, and optionally an acrylate and/or nitrogen heterocyclic monomer including those wherein the quaternary ammonium salt is a unit of the formula:wherein R is methyl or hydrogen; R4is a C1to C6alkyl group, optionally substituted with halogen, hydroxyl and alkoxy groups, X is halogen; and R1, R2and R3are independently selected from the group consisting of alkyl and alkoxy groups. Suitable nitrogen heterocyclic compounds include N-vinylpyrrolidone, N-vinylformamide, N-vinylacetamide, N-vinylcaprolactam, N-vinylimidazole and N-vinylpyridine. The copolymers have particular applicability in the control and inhibition of zinc sulfide or iron sulfide scales, typically formed when zinc bromide brines are used as fluids in the treatment of a gas or oil well, such as a completion fluid.

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