Method for increasing the molecular weight of diorganopolysiloxa

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 708

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active

046071156

ABSTRACT:
Diorganopolysiloxanes may be polymerized to increase their molecular weight by heating the siloxane in the presence of a quaternary phosphonium hydroxide, in which one of the substituents on the phosphorus atom of the phosphonium cation is a monovalent radical containing carbon, hydrogen and silicon atom(s) and possibly siloxane oxygen atoms(s) and the three remaining substituents on the phosphorus atom are the same or different hydrocarbon radicals that are free of aliphatic carbon-carbon multiple bonds.

REFERENCES:
patent: 2759008 (1956-08-01), Dunham et al.
patent: 2883366 (1959-04-01), Kantor et al.
patent: 3398117 (1968-08-01), Baronnier et al.
patent: 3398118 (1968-08-01), Baronnier et al.
patent: 4008261 (1977-02-01), Brown et al.

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