Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1993-08-24
1995-05-09
Mars, Howard T.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568699, C07C 4106
Patent
active
054141478
ABSTRACT:
A method for improving the conversion of isobutylene in the MTBE reaction process while simultaneously producing a substantially methanol-free MTBE utilizes an increased methanol to isobutylene molar ratio in the reaction process and methanol-free C4 hydrocarbons as reflux. The use of a methanol-free C4 hydrocarbon stream as reflux eliminates the excess methanol generated by increasing the methanol to isobutylene molar ratio without requiring a higher reflux ratio or changing operating conditions. The method permits isobutylene conversion of more than 98% while producing a purified MTBE with less than 0.5% methanol content.
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Curfiss Robert C.
Global Octanes Corporation
Mars Howard T.
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