Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles
Reexamination Certificate
2002-06-07
2003-10-21
McKane, Joseph K (Department: 1626)
Organic compounds -- part of the class 532-570 series
Organic compounds
Nitriles
Reexamination Certificate
active
06635781
ABSTRACT:
The present invention relates to the hemihydrogenation of dinitriles to corresponding aminonitriles.
The hydrogenation of dinitriles is generally carried out in order to prepare the corresponding diamines; thus, particularly, the hydrogenation of adiponitrile results in hexamethylenediamine, which is itself one of the base monomers in the preparation of polyamides.
However, it can sometimes prove necessary to prepare not the diamine but the intermediate aminonitrile. This is the case, for example but not limitingly, in the hemihydrogenation of adiponitrile to aminocapronitrile, which is capable of subsequently being converted either to caprolactam, the base monomer in the manufacture of polyamide-6, or directly to polyamide-6.
Thus, U.S. Pat. No. 4,389,348 discloses a process for the hydrogenation of dinitrile to &ohgr;-aminonitrile by hydrogen in ammonia and aprotic solvent medium in the presence of rhodium deposited on a basic support.
U.S. Pat. No. 5,151,543 discloses a process for the partial hydrogenation of dinitriles to aminonitriles in a solvent in molar excess of at least 2/1 with respect to the dinitrile, comprising liquid ammonia or an alkanol comprising an inorganic base which is soluble in the said alkanol, in the presence of a catalyst of Raney cobalt or nickel type.
U.S. Pat. No. 5,756,808 also discloses a catalytic process for the hemihydrogenation of dinitriles to aminonitriles. The catalysts disclosed are based on nickel, cobalt, iron, ruthenium or rhodium and are optionally used in combination with other elements known as promoter elements, such as palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismuth and the elements belonging to the rare earth metals group. This document also specifies that ruthenium, in combination or not in combination with rhodium, can be used without promoter elements. The catalysts are deposited on supports, such as alumina or silica. The degrees of selectivity for aminocapronitrile (ACN) are between 70% and 80%.
However, in order to obtain an industrial process for the preparation of aminonitrile by hemihydrogenation of a dinitrile, it is necessary to obtain even higher selectivities for aminonitrile for degrees of conversion of the dinitrile in the region of 100% and therefore to find novel catalytic systems and to find processing conditions for the hemihydrogenation which make it possible to reach or to come close to this objective.
One of the objects of the present invention, which relates to the preferential hydrogenation of a single nitrile functional group of a dinitrile (called hemihydrogenation in the present text), so as to prepare predominantly the corresponding aminonitrile and only to a minor extent the diamine, is in particular to provide a novel catalytic system which makes it possible to improve the degree of selectivity of this reaction.
More specifically, the invention relates to a process for the hemihydrogenation of aliphatic dinitriles to corresponding aminonitriles using hydrogen in the presence of a catalyst of the type comprising a catalyst deposited or adsorbed on a support, characterized in that the catalyst is based on ruthenium, the support being a charcoal obtained by pyrolysis of a paraffin oil. These charcoals are also known as acetylene black, which terminology will be used in the continuation of the text.
Thus, these acetylene blacks exhibit a lower specific surface than that of the active charcoals generally used as catalyst support.
This specific surface is generally between 50 and 100 m
2
/g. These acetylene blacks are also distinguished by other technical characteristics, such as their crystalline structure, their oxidation state, a high chemical purity and a high porosity.
Mention may be made, by way of example, as acetylene blacks which are suitable for the invention, of the blacks sold by the company SN2A under the trade names Y70, Y200, Y50 or YS.
The amounts of catalytic phases present on the support correspond to the amounts conventionally deposited in supported catalytic systems.
The use of the specific support of the invention makes it possible to obtain a high selectivity for aminonitriles for high degrees of conversion of the dinitriles. This level of selectivity cannot be achieved by using other conventional supports, such as alumina, silica or active charcoals generally of vegetable origin.
Thus, the use of this catalytic system makes it possible to achieve a degree of selectivity for aminonitriles of at least 80% for a degree of conversion of the dinitrile of greater than 60%. This degree of selectivity is greater than that obtained with a Raney nickel catalyst.
According to a novel preferred characteristic of the invention, the catalyst can be subjected to reduction by a reducing agent, such as hydrogen, for example, before introduction into the reaction mixture.
According to another embodiment of the invention, the catalyst comprises doping elements, at least one of which is iron.
The presence of these doping elements, in particular of iron, makes it possible to increase the lifetime of the catalyst and therefore the savings in the hemihydrogenation process.
The concentration of doping element with respect to the ruthenium is between 5% and 60% by weight, preferably between 10 and 30% by weight.
The doping elements other than iron which are suitable for the invention are chosen from the group comprising tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismuth, silicon, titanium, zirconium, the rare earth metals, palladium, platinum, iridium, osmium, copper, silver, chromium and molybdenum.
The aliphatic dinitriles which can be employed in the process of the invention are more particularly the dinitriles of general formula (I):
NC—R—CN (I)
in which R represents a linear or branched alkylene or alkenylene group having from 1 to 12 carbon atoms.
Use is preferably made, in the process of the invention, of dinitriles of formula (I) in which R represents a linear or branched alkylene radical having from 2 to 6 carbon atoms.
Mention may in particular be made, as examples of such dinitriles, of adiponitrile, methyl-glutaronitrile, ethylsuccinonitrile, malononitrile, succinonitrile and glutaronitrile and their mixtures, in particular the mixtures of adiponitrile and/or of methylglutaronitrile and/or of ethylsuccinonitrile which are capable of originating from the same process for the synthesis of adiponitrile.
The preferred compound of the invention is adiponitrile which makes it possible to obtain a precursor of polyamide-6 or of its monomer, caprolactam.
According to a preferred embodiment of the invention, the hemihydrogenation reaction is carried out in the presence of ammonia. This characteristic makes it possible to improve the performance of the catalytic system of the invention, in particular its lifetime.
According to another preferred characteristic of the invention, the hemihydrogenation of a dinitrile to aminonitrile can be carried out in the presence of a strong inorganic base deriving from an alkali metal element, from an alkaline earth metal element or from the ammonium cation.
Thus, the strong inorganic base is generally composed of alkali metal or alkaline earth metal hydroxides, carbonates and alkoxides or of hydroxides, carbonates and alkoxides of the ammonium cation. It is preferably chosen from alkali metal hydroxides, carbonates and alkoxides.
Preferably, the strong inorganic base employed is chosen from the following compounds: LiOH, NaOH, KOH, RbOH, CsOH, compounds comprising a quaternary ammonium radical and mixtures of these compounds. In practice, use is generally made of NaOH and KOH.
These strong bases are present in the reaction mixture according to a concentration of between 0.1 and 50 mol of OH
−
per kg of catalytic system, preferably between 5 and 35 mol of OH
−
per kg of catalytic system. In addition, this concentration is much lower, indeed even zero, w
Dallemer Frédéric
Seigneurin Aline
McKane Joseph K
Rhodia Polyamide Intermediates
Shiao Robert
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