Method for graft copolymerization to natural rubber articles

Surgery – Means for introducing or removing material from body for... – Treating material introduced into or removed from body...

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525244, 525285, 525301, 5253331, 525386, 604266, A61M 2500, C08L 5104

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045265798

ABSTRACT:
A process for grafting a hydrophilic polymer of a carboxylic acid or a salt thereof onto the surface of a natural rubber article by contacting said article in reaction inert solvent with a vinyl carboxylic acid anhydride and initiator, and subsequent washing and hydrolysis of anhydride groups to carboxylate groups and an article when prepared by the invention process.

REFERENCES:
patent: 3566874 (1977-03-01), Shepherd et al.
patent: 4347341 (1982-08-01), Bartl et al.
patent: 4382128 (1983-05-01), Li
patent: 4459318 (1984-07-01), Hyans
"Block and Graft Copolymerization", R. J. Ceresa, Editor, Wiley and Sons, New York, 1973, pp. 47-97.
Burfield et al., European Polymer, J., 14, 799 (1978).
"The Vanderbilt Rubber Handbook," R. T. Vanderbilt Company, Inc., N.Y.C. pp. 154-156, (1958).

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