Method for forming single phase, single crystalline 2122 BCSCO s

Superconductor technology: apparatus – material – process – Processes of producing or treating high temperature... – With melting

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505729, 505733, 505742, 427 62, 4274432, 156662, 423593, C30B 1902

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053148690

ABSTRACT:
A substantially single phase, single crystalline, highly epitaxial film of Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor which has a T.sub.c (zero resistance) of 83 K is provided on a lattice-matched substrate with no intergrowth. This film is produced by a Liquid Phase Epitaxy method which includes the steps of forming a dilute supercooled molten solution of a single phase superconducting mixture of oxides of Bi, Ca, Sr, and Cu having an atomic ratio of about 2:1:2:2 in a nonreactive flux such as KCl, introducing the substrate, e.g., NdGaO.sub.3, into the molten solution at 850.degree. C., cooling the solution from 850.degree. C. to 830.degree. C. to grow the film and rapidly cooling the substrate to room temperature to maintain the desired single phase, single crystalline film structure.

REFERENCES:
patent: 3939252 (1976-02-01), Pandey
patent: 5007271 (1991-04-01), Boegli
patent: 5055445 (1991-10-01), Belt et al.
Shin et al., "Superconducting Bi-Sr-Ca-C u-O films prepared by the liquid phase epitaxial method", Physica C 173 (1991) pp. 93-98.
Pandey et al., "Growth of 2122-Phase of Bi-Ca-Sr-Cu-O Superconducting Films by LPE Process and Possibility of its Growth in Microgravity Environment," Applied Superconductivity, vol. 1, Nos. 3-6, pp. 1289-1302, (no month), 1993.
Raina et al., "Phase Analysis of Bi-Ca-Sr-Cu-O Superconducting Films at Different Growth Temperatures from KC1 Supercooled Solutions", Journal of Crystal Growth, vol. 128, pp. 729-733, (no month), 1993.
Fratello, V. J., "The Growth of Oxide Films by Liquid Phase Epitaxy," Presented at the 8th International Summer School on Crystal Growth, Aug. 9-15, 1992, pp. 1-47.
Schneemeyer et al., "Growth of Superconducting Single Crystals in the Bi-Sr-Ca-Cu-O System from Alkali Chloride Fiuxes", Nature, vol. 332, Mar. 1988, pp. 422-424.
Komatsu et al., "In Situ Observations of Crystal Growth of Bi-Based Oxide Superconductors," Physica C, vol. 190, pp., 14-17, (no month), 1991.
Garbauskas et al., "High-Temperature Neutron Diffraction Study of the Melting Behavior of Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.x9," Applied Physics Letters, vol. 58, pp. 2987-2988, Jun. 1991.
Yue et al., "Liquid-Phase-Epitaxial Growth of HTSC Thin Films," SPIE vol. 1187 Processing of Films for High T.sub.c Superconducting Electronics, pp. 94-103, (no month), 1989.
K. K. Raina et al. "Thin Film Growth of the 2122-phase of BCSCO Superconductor With High Degree of Crystalline Perfection"; J. Mater. Res. vol. 7, No. 9, Sep. 1992, pp. 1-5.
S. Narayanan, et al. "Growth of BiCaSrCu-oxide Superconducting Film on NdGaO.sub.3, Substrates"; Elsevier Science Publishers B.V. vol. 11, Nos. 5,6,7; Jun. 1991, pp. 212-215.
G. Balestrino et al., "Zero Resistivity at 81 K in BSCCO Films Grown From Liquid KCl Solutions"; Elsevier Science Publishers B.V. C 162-164; (1989) pp. 115-116.
R. S. Liu et al. "Epitaxial Growth of High-T.sub.c Bi-Ca-Sr-Cu-O Superconducting Layer by LPE Process"; Japanese Journal of Applied Physics vol. 27, No. 8, Aug. 1988 pp. L1470-1472.
R. F. Belt et al. "Superconductor Film Growth of LaGaO.sub.3 Substrates by Liquid Phase Epitaxy"; Appl. Phys. Lett., vol. 56, No. 18, Apr. 1990 pp. 1804-1807.
C. S. Yang et al. "Bi-Sr-Cu-O Superconductor Films Grown By The LPE Technique"; Journal of Crystal Grown vol. 99, (1990) pp. 951-953.
G. Balestrino et al. "Epitaxial Films of BSCCO Grown From Liquid KCL Solutions Onto Several Substrates" IEEE Transactions on Magnets, vol. 27, No. 2, Mar. 1991, pp. 1589-1591.
N. Solaypappan A Thesis: "Optimization of Growth Conditions of Bi.sub.2 CaSr.sub.2 Cu.sub.2 O8.sub.+x, Superconducting Films on NdGaO.sub.3 Substrates By LPE Technique And Their Characterization"; Submitted to the Office of Graduate Studies of Texas A & M University; Dec. 1991, pp. 1-86.

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