Coating processes – Heat decomposition of applied coating or base material – Coating decomposed to form carbide or coating carbonized
Patent
1994-06-30
1996-04-02
Bell, Janyce
Coating processes
Heat decomposition of applied coating or base material
Coating decomposed to form carbide or coating carbonized
427226, 427244, 427245, 4274192, 4274197, B05D 302, B05D 5/00
Patent
active
055038735
ABSTRACT:
A method of forming inorganic membranes which are highly selective to permeation of hydrogen by temporarily forming a carbon barrier in the pores of a porous substrate, followed by chemical deposition of SiO.sub.2, B.sub.2 O.sub.3, TiO.sub.2, Al.sub.2 O.sub.3 and mixtures thereof in the pores, followed by removal of the carbon barrier. It has been demonstrated that the permeation selective layers thusly formed by this invention have a five fold increase in permeance over such layers made by a similar method but without forming a temporary carbon barrier in the pores of the porous substrate, and removal of the carbon-barrier after establishment of the oxide membrane. Some suitable porous substrate are Vycor.TM. glass or Al.sub.2 O.sub.3.
REFERENCES:
patent: 4640901 (1987-02-01), Lee et al.
patent: 4738874 (1988-04-01), Berardo et al.
patent: 4902307 (1990-02-01), Gavalas et al.
patent: 5130166 (1992-07-01), Spencer
Gavalas George R.
Jiang Shaocong
Bell Janyce
California Institute of Technology
Logan F. Eugene
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