Method for forming diffusion barrier film of semiconductor...

Coating processes – Coating by vapor – gas – or smoke – Metal coating

Reexamination Certificate

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C427S255394, C427S255700, C427S343000

Reexamination Certificate

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06849298

ABSTRACT:
A method for forming a diffusion barrier layer of a semiconductor device by using an Atomic Layer Deposition (ALD) is disclosed, which, in a method for forming a diffusion barrier layer on an entire surface of a semiconductor substrate before forming a metal pipe connected with the semiconductor substrate through a contact hole, the contact hole being formed to expose one region of the semiconductor substrate by selectively removing an insulating interlayer on the semiconductor substrate, the method includes the steps of forming Ti/TiN layers without being exposed to the air by alternately providing a precursor set by using an atomic layer deposition (ALD) and many kinds of reacting gases, performing a silane treatment on the TiN layer, and forming a Ti thin layer by the ALD.

REFERENCES:
patent: 6139700 (2000-10-01), Kang et al.
patent: 6482733 (2002-11-01), Raaijmakers et al.
patent: 6534404 (2003-03-01), Danek et al.
patent: 6566283 (2003-05-01), Pangrle et al.
patent: 6627523 (2003-09-01), Pyo

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