Method for forming cellulose

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

Reexamination Certificate

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Details

C536S102000, C536S063000, C536S076000, C536S085000, C536S124000, C428S221000, C106S206100, C162S158000, C162S068000

Reexamination Certificate

active

06921820

ABSTRACT:
A method for forming II-type cellulose, which comprises introducing together a slurry having water and a I-type cellulose dispersed therein and water in the state of high temperature and high pressure to a tubular reactor (28) contacting the I-type cellulose with a hot water in a supercritical state or subcritical state for a predetermined time in the tubular reactor (28), to thereby cleave a part of the hydrogen bonds in the I-type cellulose and dissolve the I-type cellulose into the water in a supercritical state or subcritical state, cooling a cellulose solution discharged from the tubular reactor (28) in a cooler (30) to room temperature or lower, followed by allowing to stand, to thereby precipitate crystals of II-type cellulose having a molecular weight lower than that of the I-type cellulose, and separating the resultant II-type cellulose from a solvent. The method allows the preparation of pure II-type cellulose by the use of a simple process.

REFERENCES:
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patent: B2 3042076 (2000-03-01), None
patent: WO 99/35190 (1999-07-01), None
Sasaki et al. “Cellulose hydrolysis in subcritical and supercritical water”. Journal of Supercrotical Fluids, 13, pp. 261-268, 1998.
Adschiri et al. J. Chem. Engg. Of Japan, 26, No. 6, pp. 676-680, 1993.
Adschiri et al., “Noncatalytic Conversion of Cellulose in Supercritical and Subcritical Water”, Journal of Chemical Engineering of Japan, vol. 26, No. 6, pp. 676-680, 1993.
Arai et al., “Importance of phase equilibria for understanding supercritical fluid environments”, Fluid Phase Equilibria 158-160, pp. 673-684, 1999.
Sasaki et al., “Cellulose hydrolysis in subcritical and supercritical water”, The Journal of Supercritical Fluids, pp. 261-268, 1998.
American Institute of Chemical Engineers, “Research & Development for Results: A Celebration of Innovation”, AIChE's 1999 Annual Meeting Program Book, Nov. 1999.
Tomoaki Minowa et al., “Cellulose decomposition in hot-compressed water with alkali or nickel catalyst,” Journal of Supercritical Fluids 13, 1998, pp. 253-259.

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