Method for forming a material layer in a semiconductor device us

Fishing – trapping – and vermin destroying

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437117, 437 92, 4271263, 4271265, 427169, H01L 2120, H01L 21465, B05D 512, B05D 506

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052368742

ABSTRACT:
A method is provided for forming a material layer in a semiconductor device using liquid phase deposition. A material layer such as a metal layer, a dielectric layer, a semiconductor layer or a superconducting layer is deposited by the liquid-phase thermal decomposition of a metal-organic precursor dissolved in an anhydrous organic solvent. The organic solvent has a chemical polarity corresponding to the selected metal-organic precursor and has a normal boiling point above the decomposition temperature of the selected precursor. As a result of few restrictions on the range of precursor physical properties, the present invention enables the use of a wide variety of molecular compositions which can be used for the formation of an equally wide variety of material layers. In one embodiment of the invention, a semiconductor substrate is subjected to a liquid mixture comprising a metal-substituted heterocyclic acetylacetonate precursor dissolved in tetradecane (b.p. 254.degree.C.). Depending upon the structure of the acetylacetonate, either a metal or a metal oxide film is deposited in the liquid phase on a semiconductor substrate immersed in a solution which is maintained at the decomposition temperature of the acetylacetonate precursor.

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"The Early Transition Metals", D. L. Kepert, Academic Press, New York, 1972, pp. 18-21.
"Metal Alkoxides as Precursors for Electronic and Ceramic Materials", D. C. Bradley, Chem. Rev. (8 6, p. 1317, 1989.
"Mass-spectrometeric Investigation of the Termal-Decompostion of Various Organosilicon Compound in SiXC1-X(H) Chemical Vapor-Deposition":, J. P. Gerault, J. Anal. Appl. Pyrolysis (4), p. 59, 1982.

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