Method for fluorination of uranium oxide

Chemistry of inorganic compounds – Radioactive – Uranium compound

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C01G 4306

Patent

active

047042613

ABSTRACT:
Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

REFERENCES:
patent: 2535572 (1950-12-01), Hainer
patent: 2804369 (1957-08-01), Fowler
patent: 2810626 (1957-10-01), Fowler

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