Semiconductor device manufacturing: process – Chemical etching – Vapor phase etching
Reexamination Certificate
2001-01-19
2003-05-06
Powell, William A. (Department: 1765)
Semiconductor device manufacturing: process
Chemical etching
Vapor phase etching
C438S724000, C438S742000, C438S754000, C438S756000
Reexamination Certificate
active
06559059
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of manufacturing a MOS transistor of an embedded memory, and more particularly, to a manufacturing method of a MOS transistor of an embedded memory to simultaneously form a periphery circuit region and a memory array area.
2. Description of the Prior Art
With increasing integration, the present trend of manufacturing semiconductor integrated circuits is to integrate memory cell arrays and high-speed logic circuit elements onto a single chip. An embedded memory composed of memory arrays and logic circuits significantly reduces the circuit area and increases the signal processing speed. The high-speed logic circuit element is also called a periphery circuit region.
Because the MOS transistors formed in the periphery circuit region requires low resistance and high speed, the present semiconductor process primarily uses a self-alignment silicide (salicide) process to form a silicide layer on each gate, source and drain of the MOS transistors formed on the periphery circuit region for reducing the surface resistance of each gate, source and drain of the MOS transistors. However, the self-aligned-contact (SAC) process developed for solving the electrical connection problem of memory cells in the memory array area involves forming a silicon nitride layer, as a cap layer, and a spacer on the top and side surfaces of a gate of a pass transistor formed in the memory array area as an isolation mask in the subsequent SAC process. Therefore, in the prior art method, the two processes conflict and are not performed simultaneously, resulting in increased time and cost.
Please refer to 
FIG. 1
 to 
FIG. 9
 
FIG. 1
 to 
FIG. 9
 are cross-sectional diagrams of a prior art method for manufacturing a metal-oxide-semiconductor (MOS) transistor of an embedded memory on a semiconductor wafer 
10
. As shown in 
FIG. 1
, the surface of the silicon substrate 
16
 is divided into a memory array area 
12
 and a periphery circuit region 
14
, and each region is separated by several shallow trench isolation structures 
11
. The prior art method involves forming a dielectric layer 
18
, a polysilicon layer 
20
 and an etching barrier layer 
22
, respectively, on the surface of the semiconductor wafer 
10
. Then, as shown in 
FIG. 2
, a mask layer 
24
 is formed over the etching barrier layer 
22
 in the periphery region 
14
. The etching barrier layer 
22
 and the polysilicon layer 
20
 in the memory array area 
12
 are removed using an isotropic wet etching operation.
As shown in 
FIG. 3
, the mask layer 
24
 above the etching barrier layer 
22
 is removed, and then the dielectric layer 
18
 in the memory array region 
12
 is stripped away to expose the substrate surface 
16
. As shown in 
FIG. 4
, a dielectric layer 
26
 is formed over the exposed substrate 
16
, and serves as a gate oxide layer in the memory array area 
12
. Thereafter, a polysilicon layer 
28
, a tungsten silicide layer 
30
 and a silicon nitride layer 
32
 are formed, respectively, over the surface of the semiconductor wafer 
10
.
In the next step, as shown in 
FIG. 5
, a photoresist layer 
34
 is deposited over the silicon nitride layer 
32
 and a lithographic process is performed to define gate patterns in the memory array area 
12
 and periphery circuit region 
14
. Next, using the photoresist layer 
34
 as a mask, the silicon nitride layer 
32
, the tungsten silicide layer 
30
 and the polysilicon layer 
28
 are etched, thereby exposing portions of the dielectric layer 
26
 in the memory array area 
12
 and portions of the etching barrier layer 
22
 in the periphery circuit region 
14
. As shown in 
FIG. 6
, the photoresist layer 
34
 is removed. Thereafter, another photoresist layer 
36
 is deposited over the memory array area 
12
 for protecting the gate 
33
 structure, which includes the dielectric layer 
26
, the polysilicon layer 
28
, the tungsten silicide layer 
30
 and the silicon nitride layer 
32
.
As shown in 
FIG. 7
, the photoresist layer 
36
 and the silicon nitride layer 
32
 of the periphery circuit region 
14
 are used as hard masks to remove the etching barrier layer 
22
 and the polysilicon layer 
20
 not covered by the silicon nitride layer 
32
 in the periphery circuit region 
14
. A gate 
35
 structure of the periphery circuit region 
14
 is formed, and the silicon nitride layer 
32
, the tungsten silicide layer 
30
, the polysilicon layer 
28
 and the photoresist layer 
36
 are then removed.
As shown in 
FIG. 8
, an ion implantation process is performed to form lightly doped drain (LDD) 
38
 structures of the MOS transistors. Next, a silicon nitride layer 
43
 is deposited over the semiconductor wafer 
10
, followed by an anisotropic etching process to form spacers 
44
 on the walls of the gate 
35
 structures in the periphery circuit region 
14
. The remaining etching barrier layer 
22
 is removed after the formation of the spacers 
44
. A source 
40
 and a drain 
42
 of the MOS transistors are then formed in the periphery circuit region 
14
. Finally, as shown in 
FIG. 9
, a self-aligned silicide operation is carried out to form a salicide layer 
46
 above each source 
40
, drain 
42
 and gate 
35
 structure in the periphery circuit region 
14
.
However, in 
FIG. 5
 of the prior art method, the etching process is simultaneously performed in the memory array area 
12
 and in the periphery circuit region 
14
 to simultaneously form patterns of the gates. The density of the gates in the memory array area 
12
 is normally greater than that of the periphery circuit region 
14
, resulting in the etching process causing both a proximity effect and a loading effect. As well, in 
FIG. 7
, an extra step is needed to remove the silicon nitride layer 
32
 in the periphery circuit region 
14
, when the silicon nitride layer 
32
 is not necessary for the gates 
35
 in the periphery circuit region 
14
.
SUMMARY OF THE INVENTION
It is a primary objective of the present invention to provide a method of manufacturing a MOS transistor of an embedded memory to solve the above-mentioned problems.
The method of the present invention involves first defining a memory array area and a periphery circuit region on the surface of the semiconductor wafer and to sequentially deposit a gate oxide layer, an undoped polysilicon layer and a dielectric layer. Next, the undoped polysilicon layer in the memory array area is implanted to form a doped polysilicon layer, followed by the removal of the dielectric layer in the memory array area. Thereafter, a metallic silicide layer and a passivation layer are formed, respectively, on the surface of the semiconductor wafer, and the passivation layer, the metallic silicide layer and the doped polysilicon layer are then etched to form a plurality of gates in the memory array area. Next, the passivation layer, the metallic silicide layer and the dielectric layer in the periphery circuit region are removed. Finally, the undoped polysilicon layer is etched to form a plurality of gates in the periphery circuit region, followed by the respective formation of spacers, sources and drains of each MOS transistor in the periphery circuit region.
There are two advantages of the present invention, the first of which is the simultaneous formation of the silicon nitride layer necessary for the gates in the memory array area and removal of the silicon nitride layer not necessary for the gates in the periphery circuit region. In the prior art method, after etching the gates in both the memory array area and in the periphery circuit region, an extra step is needed to remove the silicon nitride layer not necessary for the gates in the periphery circuit region to increase time cost. The second advantage is that the present invention performs the etching process to form separately the gates in the memory array area and those in the periphery circuit region to reduce both the proximity effect and the loading effect since the density of gate patterns of the DRAM is higher in the memory array than in the periphery circuit regio
Chien Sun-Chieh
Kuo Chien-Li
Hsu Winston
Powell William A.
United Microelectronics Corp.
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