Method for extending catalyst life in processes for...

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – Having alkenyl moiety – e.g. – styrene – etc.

Reexamination Certificate

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C585S440000

Reexamination Certificate

active

06936743

ABSTRACT:
Disclosed is a method for extending the life of dehydrogenation catalysts used to prepare vinyl aromatic hydrocarbons. The catalysts, which typically include both iron oxide and potassium containing catalysis promoter, are exposed to additional potassium delivered using a potassium carboxylate. The potassium carboxylates are desirably free of halogens and other catalysts poisons or groups that could result in the undesirable properties in vinyl aromatic hydrocarbons produced therewith. The present invention is particularly useful with the production of styrene and methyl styrene.

REFERENCES:
patent: 4590324 (1986-05-01), Satek
patent: 5503163 (1996-04-01), Boyd
patent: 5689023 (1997-11-01), Hamilton, Jr.
patent: 5689027 (1997-11-01), Abichandani et al.
patent: 5739071 (1998-04-01), Chen et al.
patent: 6184174 (2001-02-01), Rubini et al.
http://www.cheresources.com/polystymonzz.shtml;Styrene Monomer Production(Dow Process).

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