Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Organic component
Reexamination Certificate
2000-06-30
2002-05-21
Griffin, Steven P. (Department: 1754)
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Organic component
C423S210000, C423S219000, C204S157300, C204S168000
Reexamination Certificate
active
06391272
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to a method for cleaning exhaust air containing pollutants, especially gaseous hydrocarbon emissions in an exhaust duct, by the use of ultraviolet (UV) radiation which raises the energy level of the hydrocarbons, and by the use of a catalyst and to an apparatus for the practice of such a method.
Published German Patent Application No. DE 4,317,199 A1 discloses a method for ultraviolet excitation of pollutants with simultaneous catalytic decomposition, in which the electrochemical potential of the reactive substances is increased by means of ultraviolet radiation and an exothermal chemical process is initiated. By a special mixing technique the excited compounds are passed over a catalytically active surface while in the excited state, where they react under the direct action of the ultraviolet radiation. This method, however, has the disadvantage that nothing other than an elevation of the electrochemical potential of the reactive substances is accomplished. At the same time a direct ultraviolet catalyst is performed, making it necessary to expose the entire active surface of the catalyst to the ultraviolet radiation. The result is that only a very small catalyst surface is available, so that for this reason alone the efficiency of the method is greatly limited. It is not possible to increase the throughput of the process by adding an additional catalyst chamber at the outlet.
U.S. Pat. No. 5,463,170 (=DE 4,305,344) describes the decomposition of highly toxic halogenated compounded contained in gases by means of oxidation, using hydrogen peroxide. This document also discloses that PCDD's and PCDF's can be decomposed by treating the gases with hydrogen peroxide with simultaneous exposure to ultraviolet light. Also, the gas is passed, in the presence of hydrogen peroxide, over a substantially inorganic solid catalyst, especially Pyrogene or precipitated silicic acid or aluminum silicate. Although the pollutant content can be considerably reduced in this manner, it is a disadvantage that the apparatus cost is very high and can only be justified when there is a need to remove highly concentrated and highly toxic pollutants.
Published German Patent Application No. DE 4,423,397 A1 also discloses a method and an apparatus for cleaning exhaust gases, in which the gases are exposed simultaneously to an electrical gas discharge between electrodes and to contact with catalytic material so that a catalytic oxidation is performed. Here, again, simultaneity greatly limits the efficiency of the process.
SUMMARY OF THE INVENTION
It is an object of the invention to provide a method and an apparatus for cleaning exhaust air which will be distinguished by simple construction.
It is a further object of the invention to provide a method and apparatus for cleaning exhaust air which has a low energy input requirement.
These and other objects have been achieved in accordance with the present invention by providing a method for decontaminating air which contains oxidizable pollutants, comprising the steps of exposing the pollutant-containing air in a first zone to UV-C radiation having a first wavelength under 300 nm which excites pollutant molecules to higher energy levels and increases their reactivity, and a second wavelength of about 185 nm which promotes the formation of ozone, the ozone decomposing to molecular oxygen and oxygen radicals which in turn effect at least partial gas phase oxidation of the pollutants; and thereafter subjecting air from the first zone to a catalytic oxidation treatment on an oxidation catalyst in a subsequent second zone wherein pollutant molecules are adsorbed on an active surface of the catalyst and oxidized to harmless reaction products, which in turn are released into the treated air.
In accordance with a further aspect, the objects of the invention are achieved by providing an apparatus for decontaminating air which contains oxidizable pollutants, comprising a first reaction zone through which air to be treated may be passed, the first reaction zone containing at least one UV radiator which emits UV-C radiation having a first wavelength under 300 nm which excites pollutant molecules to higher energy levels and increases their reactivity, and a second wavelength of about 185 nm which promotes the formation of ozone, and a second reaction zone in communication with an outlet of the first reaction zone and containing an oxidation catalyst which promotes catalytic oxidation of pollutant molecules.
In some preferred embodiments of the invention the first reaction zone is provided with a reflective surface for reflecting the UV radiation; the second reaction zone is followed by a third reaction zone containing at least one corona discharge electrode for ionizing the exhaust gas; and the exhaust duct is provided with a sensor and regulator for adjusting the UV radiation to an optimum level.
Since the exhaust air is subjected in the first section of the air duct to UV-C radiation having a wavelength of less than 300 nm, preferably about 254 nm, which causes an excitation of the hydrocarbons to higher energy levels, and furthermore to UV-C radiation having a wavelength of preferably about 185 nm, which additionally causes the formation of ozone, and of molecular oxygen and radicals from the ozone, whereby a partial oxidation of the hydrocarbon molecules takes place in the gas phase, and since in an adjoining second section of the air duct a catalytic oxidation of the hydrocarbon molecules is carried out on the inside surface of a catalyst formed of porous support material, in which the hydrocarbon molecules are adsorbed, then oxidized on the active surface by the additionally formed ozone and removed from the surface of the catalyst in the form of H
2
O and CO
2
as reaction products, a very effective catalytic oxidation of the pollutants has surprisingly been achieved even at room temperature.
Basically, the UV-C radiation having a wavelength of preferably about 185 nm in the first section of the air duct causes the formation of large amounts of ozone which is available as reactant, and which additionally leads in the second section to a very advantageous, intensified catalytic oxidation of the hydrocarbons. Thus, high concentrations of hydrocarbons can be decomposed therein. Simultaneously, however, excess ozone is decomposed to molecular oxygen on the surface of the catalyst. In an entirely surprising manner, the excess ozone produced consequently does not cause any of the environmental harm that might have been expected.
The method of the invention is furthermore distinguished by the fact that, at throughputs between 1,000 and 10,000 m
3
/h, comparatively simple means permit the achievement of a high degree of purification, and the pollutants are disposed of as reaction products in the form of H
2
O and CO
2
. Conventional methods for comparable throughputs are decidedly more complicated and expensive.
According to one preferred embodiment of the method, UV radiation having wavelengths of 185 nm and 254 nm is used. The 185 nm wavelength serves mainly to produce ozone. The 254 nm wavelength serves primarily to excite the hydrocarbons. By such an arrangement of the UV radiation it is possible to produce both of these effects in an extremely effective manner. If desired, an additional intensification of the formation of ozone can be achieved by ionization with corona discharges additionally produced especially in the first section of the air duct.
Especially if the cleaned exhaust air is to be delivered as an air supply to interior spaces, it has been found advantageous if the exhaust air additionally is ionized in a subsequent, third section of the apparatus. By enriching the air with oxygen ions in this way, it is possible to improve the quality of the air, especially air for breathing.
It is furthermore envisioned that the catalytic oxidation preferably is performed by active carbon. The advantage is that the active carbon can be reactivated inexpensively. Furthermore, active carbon can be used very c
Crowell & Moring LLP
Griffin Steven P.
Medina Maribel
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