Method for ether formation

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568585, 568931, C07C 4300, C07C20500

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active

054751497

ABSTRACT:
A process for the preparation of 4,4'-dinitro-2,2'-di(trifluoromethyl)diphenyl ether according to the equation ##STR1## where X is F, Cl, Br or I, where the inorganic base is selected from the group consisting of alkali metal hydroxides, alkali metal carbonates, and alkali metal bicarbonates, in the presence of a catalytic quantity of a benzoate catalyst. 2,8-Dinitro-6,6,12,12,-tetrafluoro-6H,12H-dibenzo[b,f][1,5]dioxocin, the corresponding diamine and polyimides formed from the diamine are also disclosed.

REFERENCES:
patent: 4558164 (1985-12-01), Jones et al.
patent: 4700011 (1987-10-01), Pillsbury
Maki and Inukai; Gov. Ind. Res. Inst. Nagoya, Nagoya, Japan Nippon Kagaku Kaishi (3) 675-7 (Japan) 1972.
Filler et al., J. Org. Chemistry, vol. 26, pp. 2707-2710 (1961).

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