Method for enriching a middle isotope using vibration-vibration

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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2041572, 20415721, 423 2, B01D 5934

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048013650

ABSTRACT:
Method for producing isotopically enriched material by vibration-vibration excitation of gaseous molecules wherein a middle mass isotope of an isotopic mixture including lighter and heavier mass isotopes preferentially populates a higher vibrational mode and chemically reacts to provide a product in which it is enriched. The method can be used for vibration-vibration enrichment of .sup.17 O in a CO reactant mixture.

REFERENCES:
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patent: 4142955 (1979-03-01), Rich et al.
patent: 4163199 (1979-07-01), Treanor
S. O. Macheret et al., Dokl. Akad. Nauk SSSR 255, 98-102 (Nov. 1980), Am. Inst. of Physics 1981.
"C.sub.2 and CN Formation by Optical Pumping of CO/Ar and CO/N.sub.2 /Ar Mixtures at Room Temperture", J. William Rich and Richard C. Bergman, Chemical Physics, vol. 44, No. 1, Nov. 15, 1979.
"Vibrational Relaxation of Anharmonic Oscillators with Exchange-Dominated Collisions", C. E. Treanor, J. W. Rich and R. G. Rehm, The Journal of Chemical Physics, vol. 48, No. 4, Feb. 15, 1968.
"Isotope Effect in the Kinetics of Nonequilibrium Plasmochemical Reactions", S. O. Macheret, V. D. Rusanov, A. A. Fridman and G. V. Sholin, Sov. Phys. Dokl. 25 (11), Nov. 1980 (1981 American Institute of Physics).
"9. Isotope Separation by Vibration-Fibration Pumping", J. W. Rich and R. C. Bergman, Nonequilibrium Vibrational Kinetics, Topics in Current Physics, vol. 39 (M. Capiltelli, Editor), published by Springer-Verlag, Berlin, 1986.

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