Method for eliminating mercaptan from crude gas

Gas separation: processes – Liquid contacting – Inorganic gas – liquid particle – or solid particle sorbed

Reexamination Certificate

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C095S236000, C095S291000, C095S291000, C095S223000, C095S181000, C095S199000, C423S228000, C423S229000, C423S243010, C423S242600

Reexamination Certificate

active

10505493

ABSTRACT:
This invention relates to a process for cleaning gas, in particular hydrocarbonaceous gas such as e.g. natural gas, which is contaminated with sulfur in the form of H2S and mercaptans as well as CO2.To remove the undesired sulfur-containing substances in the form of H2S and mercaptan from crude gas, it is proposed in accordance with the invention that the crude gas is introduced into an absorption and regeneration column and washed therein, three gas streams being withdrawn from this absorption and regeneration column, a first exhaust gas stream being introduced into a Claus plant, a second sour gas stream with a low H2S concentration being introduced into another absorption plant, and a third gas stream, the valuable gas with the mercaptans, being cooled and supplied to an adsorption plant, that from this adsorption plant a cleaned valuable gas is withdrawn, and a mercaptan-containing gas stream is subjected to washing, that this concentrated mercaptan-containing gas is supplied to the Claus plant.

REFERENCES:
patent: 3989811 (1976-11-01), Hill
patent: 4372925 (1983-02-01), Cornelisse
patent: 4552572 (1985-11-01), Galstaun
patent: 4957715 (1990-09-01), Grover et al.
patent: 6740230 (2004-05-01), Hugo et al.
patent: WO 97/26069 (1997-07-01), None
patent: WO 97/26070 (1997-07-01), None

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